You take the glass stopper and stick the tapered end into that hole on top of the bottle. Thats how they work.

Sorry I couldnt resist.
Actually Ive used them and never had a problem other than breakage more due to the way I carried them. The reason Im not using them now is all the bottles I had glass stoppers for have broken. I broke a few by them getting hit on the top of the stopper. The necks of the bottles broke. Im using corks now in my collodion and varnish bottles but as you probably know they can fall apart and leave pieces of cork in the collodion.